Ph.D opportunity in igneous isotope geochemistry at SMU

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From: Rita Economos <rita.economos@xxxxxxxxx>

4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4-4

Dear Volcanological community,

We are soliciting applications for a Ph.D. student at Southern Methodist
University in Dallas, Texas, to begin Fall of 2019, who will play a key
role in an NSF-funded project on â??Sulfur Isotope Systematics and Oxygen
Fugacity Evolution in the 1257 CE Samalas Magma Reservoir, Indonesiaâ?? (see
project abstract below). The selected Ph.D. student will be based at SMU
under the primary supervision of Dr. Rita Economos. Other project
participants include Drs. Marc-Antoine Longpré and Shuo Ding at Queens
College, City University of New York. The project will be conducted in
close collaboration with Dr. Céline Vidal (University of Cambridge), IPGP
(France) and CVGHM (Indonesia) and Adrian Fiege (AMNH). Current plans for
the Ph.D. project will focus on SIMS data collection and interpretation of
stable isotope ratios in multiple magmatic phases, particularly apatites,
but the project includes several additional cutting-edge analytical
opportunities depending on the interests of the student.

Applicants should follow the procedures for application for Graduate Study
at Southern Methodist University by January 15th, 2019. Contact Rita
Economos for additional information at reconomos@xxxxxxx.



*Project abstract:*

Sulfur is the third most abundant volatile element in volcanic systems
following water and CO2. Release of sulfur to the atmosphere during
volcanic eruptions can perturb climate on a global scale and cause acid
rain, resulting in significant environmental impact. The eruption of Mt.
Samalas on Lombok Island, Indonesia, in 1257 CE generated the largest
volcanic sulfur emission event of the last 2000 years. This event is
coincident with a multi-year global cooling event around the beginning of
the â??Little Ice Ageâ??. The central research question of this project is: how
did this volcano build up so much eruptible sulfur? The scientist
participants will test hypotheses of sulfur enrichment mechanisms by
probing deep into sulfurâ??s properties and behavior within sulfides,
apatites, and volcanic glasses (rapidly cooled melts) from pumice samples
from this eruption. The project will utilize the most advanced analytical
techniques to investigate sulfur chemistry, many of which were developed
recently by participants on the research team. This project will yield new
insights into the capability of magmatic systems beneath volcanoes to
accumulate reservoirs of eruptible sulfur large enough to create
significant global environmental impacts.

The project exploits the complex geochemical behavior of sulfur to track
its movement from the liquid phase (silicate melt) into solid (mineral) and
gas phases in magmatic systems. Sulfur is a polyvalent element that can
change its valence state from S2- to S6+ over a narrow redox range relevant
for terrestrial magmatic systems. This makes sulfur an excellent tracer for
changes in magma redox conditions that may have played a critical role in
the transport, enrichment, and release of sulfur during the 1257 Mt.
Samalas eruption. The involved magmatic processes (e.g., degassing) should
lead to predictable fractionations of sulfur isotopes in glasses and
minerals, which will further constrain the dynamics of sulfur build-up at
Samalas. The valence states of sulfur in minerals and glasses will be
determined via X-ray absorption near-edge structure (XANES) spectroscopy,
whereas sulfur isotope ratios will be measured by secondary ionization mass
spectrometry (SIMS). This dovetailing of redox and isotope studies is a
powerful new approach to addressing sulfur-related science questions. This
project will serve as a blueprint for future studies of other volcanic
systems and will have implications for magmatic sulfide ore-forming
processes and crustal magma evolution of interest to the broader earth
science community.

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