MySQL query to generate Array

["Tony Devlin" <tdevlin@xxxxxxxxxxxxx>]

How do you setup a mysql query to generate an array?
 
I want to take URL and URLName from a database and use it to create an array
called links.
 
I know how to do the array and the mysql seperately, I don't know how to
make the results of 
the mysql become the key=>value pairs in the array.
 
Any help is appreciated
 
--Tony