You can actually reduce the time more by pre-syncing to the new location....something like:rsync -va /var/lib/pgsql/ /var/lib/pgsql2/service postgres stoprsync -va /var/lib/pgsql/ /var/lib/pgsql2/The second rsync will only copy the deltas from the first, it still has to go in and determine what needs to be copied/what changed but the bulk of it can be prepared/migrated before the actual downtime window.
If you *really* want to do a fast switch and your configuration disk configuration supports it you could possibly play games with using single-machine DBRD or LVM RAID to live-sync the old and new directories. Of course it's equally possible that the setup involved to do this will involve more initial downtime than just copying the files.
Another possibility is to set up an additional slave instance of PostgreSQL on your master machine then cut over to that instance. I haven't though through the issue of bringing up your actual slave servers after the cutover. I suspect in the worse case you would have your current master instance, your replica instance running on the master server and using the new SSD then migrate the slave servers to cascade off the master server's replica instance. When all is synched up, promote the master server replica instance to a master and kill off the original master instance.
As always in these instance, testing and practice is mandatory.
Cheers,
Steve