Ok, ran into a couple of problems:
1. You don't actually get all 25GB after formatting, you get 24.8GB so I needed to modify the dd line to:
$ dd if=/dev/zero of=./picback.udf bs=2048 count=12088320
2. Brasero now doesn't tell me that my image is too big for my disc, but still refuses to write.
Now to see if I can get cdrtools to play nice (or replace cdrkit) or give up and put it in /usr/local and hope brasero can find it there.
Richard
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